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There is no known toxicity of thiamine.

Dhir  S  et al. Neurological, psychiatric, and biochemical aspects of thiamine deficiency in children and adults. Front Psychiatry. 2019;10:207.
[PubMed: 31019473]  
Smith  TJ  et al. Thiamine deficiency disorders: a clinical perspective. Ann N Y Acad Sci. 2021;1498:9.
[PubMed: 33305487]  

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