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There is no known toxicity of riboflavin.

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Manole  A  et al. Clinical, pathological and functional characterization of riboflavin-responsive neuropathy. Brain. 2017 Nov 1; 140(11):2820–37.
[PubMed: 29053833]  
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Saedisomeolia  A  et al. Riboflavin in human health: a review of current evidences. Adv Food Nutr Res. 2018;83:57–81.
[PubMed: 29477226]  

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